Search results for "proton exchange"
showing 10 items of 63 documents
Impact of Ir modification on the durability of FeNC catalysts under start-up and shutdown cycle conditions
2022
A common problem associated with FeNC catalysts is their poor stability dominated by the carbon oxidation reaction (COR). In this work, the feasibility of stabilizing FeNC catalysts with small quantities of Ir was explored. With iridium being present, instead of COR the oxygen evolution reaction should be favored. The impact on structure and morphology was investigated by 57Fe Mössbauer spectroscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and transmission electron microscopy. The catalytic activity and durability for the oxygen reduction reaction was evaluated by rotating ring disc electrode experiments and accelerated stress tests mimicking the start-up and shutdown cycle (SS…
Dual-polarization-pump CW laser operation in Nd3+:LiNbO3 channel waveguides fabricated by reverse proton exchange
2008
Abstract In this work, continuous-wave laser action at 1084.5 nm at room temperature in LiNbO 3 :Nd 3+ channel waveguides, fabricated by reverse proton exchange (RPE), is reported. The sample was pumped at λ = 808 nm in either σ or π-polarized configurations, TE- and TM-pumping schemes, being the laser emission π-polarized at all power levels. The laser characteristics, as function of the pumping scheme (TE or TM), have been obtained. In both cases, the laser emission was stable, without any reduction in the output power even under continuous pump operation at maximum power at room temperature, indicating high resistance to photorefractive damage.
Double cross-linked polyetheretherketone proton exchange membrane for fuel cell
2012
Abstract The proton exchange membrane based on polyetheretherketone was prepared via two steps of cross-linking. The properties of the double cross-linked membrane (water uptake, proton conductivity, methanol permeability and thermal stability) have been investigated for fuel cell applications. The prepared membrane exhibited relatively high proton conductivity, 3.2 × 10 −2 S cm −1 at room temperature and 5.8 × 10 −2 S cm −1 at 80 °C. The second cross-linking significantly decreased the water uptake of the membrane. The performance of direct methanol fuel cell was slightly improved as compared to Nafion ® 117 due to its low methanol permeability. The results indicated that the double cros…
Ab initio molecular dynamics study of overtone excitations in formic acid and its water complex
2018
In this article, we present results from ab initio molecular dynamics simulation of overtone excitation in formic acid monomer and its water complex in the gas phase. For the monomer, a conformation change is observed employing both OH and CH vibrational excitations, which supports experimental findings. In the formic acid–water complex, interconversion also takes place, but it proceeds via hydrogen exchange rather than via intramolecular reaction. Simulations raise a question on effect of quantum and matrix effects to the results. Also, a brief test of different computation methods was done on the system. peerReviewed
MATLAB-based simulator of a 5 kW fuel cell for power electronics design
2013
Abstract In the last few years, renewable energies have been encouraged by worldwide governments to meet energy saving policies. Among renewable energy sources, fuel cells have attracted much interest for a wide variety of research areas. Since combined heat-power generation is allowed, household appliances are still the most promising applications. Fuel cell-based residential-scaled power supply systems take advantage by simultaneous generation of power and heat, reducing the overall fossil fuel consumption and utilities cost. Modelling is one of the most important topic concerning fuel cell use. In this paper, a measurement-based steady-state and dynamic fuel cell model is presented. The …
Preliminary Tests On A Miniaturized Hybrid Pv-Pemfc System
2007
A regenerative hybrid PV-PEMFC low power system is a suitable solution to replace batteries and to supply small electric devices placed in remote areas with no grid connection. Such a system was designed and built including a PV array, electrolyzer, PEMFC stack (6We) and hydrogen storage tank. As well known a hybrid PV-PEMFC energy system may represent a reliable solution to the renewable energy storage problem. Hydrogen produced by such a system is a clean fuel, suitable to replace traditional fuels which contain carbon damaging the environment. The paper reports results of a preliminary, non-dynamic experimental analysis performed on the system in order to study the effects of the anode p…
PEM electrolyzer characterization with carbon-based hardware and material sets
2021
Abstract The research and development of proton exchange membrane water electrolysis (PEMWE) is an upcoming and growing area due to a rising interest in hydrogen as an energy carrier. Operating conditions are harsher than in a fuel cell system, particularly because the potentials required for the oxygen evolution reaction are significantly higher. In commercial water electrolysis systems, this is compensated by typically using titanium material sets that are often protected against oxidation through coating processes. Such material choices make small scale research hardware and porous transport layers expensive and difficult to source. In this work, we show that the stability of traditional…
Fuel cells for household appliances: Experimental test of power management algorithms
2013
In this paper, fuel cell - based hybrid power supplies for household appliances are addressed. The profile of residential power consumption is evaluated during working, non-working days in both summer and winter periods. The worst-case load power demand is therefore highlighted. A 5kW Nuvera PowerFlow proton exchange membrane fuel cell for household appliances is tested. On the basis of the characterization of the fuel cell stack under test, stand-alone and fuel cell - battery active hybrid power supply architectures are both considered. Experimental validation of three power management algorithms is proposed in terms of hydrogen consumption, cost and energy saving. Power management algorit…
Design of a LLC Resonant Converter for Powering a PEM Electrolyzer
2021
International audience; This paper proposes the design of a LLC resonant converter to supply a proton exchange membrane (PEM) electrolyzer. The PEM requires a low voltage with high current, a reduced output voltage ripple, and an overdamped dynamic behavior of the converter to avoid voltage overshoots. The designed converter allows satisfying the design constraints, minimizing switching and reverse recovery losses; the efficiency is influenced mainly by the output rectifier's conduction losses.
PBI-based composite membranes for polymer fuel cells
2010
Abstract In the present study poly(2,2-(2,6-pyridin)-5,5-bibenzimidazole) was used for the preparation of novel MEAs for high-temperature polymer fuel cells (HT-PEMFCs). We prepared hybrid materials with two types of silica fillers in order to increase the MEA performances using this polymer. The membranes were characterized in terms of their microstructure and thermal stability. Cell operation tests and Electrochemical Impedance Spectroscopy were used for the characterization of the MEAs. A maximum power density of about 80 mW cm−2 was obtained at 300 mA cm−2 by using an imidazole-modified silica filler. The EIS technique showed that the fillers chiefly help to reduce the charge transfer r…